姓 名：李法宝
出生年月：1978年6月
职务职称：副教授，硕士生导师
专业方向：有机化学
办公电话：02750865342
Email：lfb0615@hubu.edu.cn
研究领域与兴趣：
富勒烯化学、过渡金属催化有机新反应、有机功能光电材料合成与应用
迄今为止，在富勒烯化学修饰及光电转换领域，已先后在国内外重要期刊发表SCI权威论文46篇，其中43篇论文发表在影响因子大于3.0的国际期刊Advanced Energy Materials(IF=29.70),Journal of Materials Chemistry A(IF=14.51),ACS Applied Energy Materials(IF=6.96),Organic Letters(IF=6.07), Advanced Synthesis & Catalysis(IF=5.98),Chinese Journal of Chemistry(IF=5.56),The Journal of Organic Chemistry(IF=4.20),Organic & Biomolecular Chemistry(IF=3.89)等上。此外，在著名百科全书Kirk-Othmer Encyclopedia of Chemical Technology,Encyclopedia of Physical Organic Chemistry及Handbook of Fullerene Science and Technology上撰写富勒烯专章共3部。
教育与研究经历：
2007.06–2010.06在中国科学技术大学博士后流动站工作，2002.09–2007.06在中国科学技术大学有机化学专业硕博连读，获理学博士学位；2010年7月加入威廉希尔体育app下载(科技)有限公司。现为威廉希尔体育app下载有机功能分子合成与应用教育部重点实验室研究人员。
教学情况：
承担本科生《有机化学》、《有机化学实验》等课程教学及辅导工作
承担项目与课题：
1.主持国家自然科学基金面上项目：基于低成本醛、胺新型富勒烯团簇材料的制备及其在钙钛矿光伏玻璃界面调控中的应用研究（22271083）
2.主持国家自然科学基金青年项目：新型富勒烯碳杂化合物的合成及其衍生化研究（21102041）
3.主持湖北省教育厅科学技术研究计划重点项目：新型富勒烯反应的开发及其在光电材料合成中的应用研究（D20161007）
4.主持湖北省自然科学基金面上项目：新型富勒烯-卟啉光电材料研究（2014CFB550）
5.主持硅酸盐建筑材料国家重点实验室（武汉理工大学）开放基金：富勒烯衍生物对钙钛矿光伏玻璃的界面调控（SYSJJ2019-10）
6.主持波谱与原子分子物理国家重点实验室（中国科学院武汉物理与数学研究所）开放基金：基于低成本醛/胺新型富勒烯光伏材料的合成与表征（T151905）
7.主持省部共建生物催化与酶工程国家重点实验室（威廉希尔体育app下载）开放基金：光酶催化新型富勒烯氮杂螺环化合物的设计、合成与表征（SKLBEE2021026）
8.主持湖北省教育厅科学技术研究计划优秀中青年人才项目：新型含氮/氧富勒烯化合物的合成研究（Q20120113）
9.主持有机功能分子合成与应用教育部重点实验室（威廉希尔体育app下载）开放基金：基于低成本醛/胺新型富勒烯反应的开发（KLSAOFM1706）
10.主持有机功能分子合成与应用教育部重点实验室（威廉希尔体育app下载）开放基金：基于富勒烯新型光电材料的合成及性能研究（2015-KL-005）
11.主持有机功能分子合成与应用教育部重点实验室（威廉希尔体育app下载）开放基金：基于氮丙啶富勒烯新反应的开发（2013-KL-010）
12.主持中国博士后科学基金：Fe(III)促进的[60]富勒烯1,3-二氧五环化合物的合成研究（20080440715）
13.主持中国科学院王宽诚博士后工作奖励基金：Fe(III)促进的C60与丙二酸酯及醛酮类化合物的自由基反应研究（2007）
14.主持教育部与湖北兴发化工集团股份有限公司产学合作协同育人项目：新型富勒烯复合材料在污水处理中的除磷研究（201801081007）
15.主持威廉希尔体育app下载自然科学基金：新型富勒烯碳杂化合物的合成及其衍生化研究（2010）
16.主持威廉希尔体育app下载教学改革研究项目：科技创新与实践教学相融合的拔尖创新型人才培养模式探索与实践（2021037）
17.主持威廉希尔体育app下载创新创业竞赛重点项目：基于功能化富勒烯调控的高效稳定钙钛矿光伏玻璃（2022年第一批）
获奖与荣誉：
1.中国科学院经理优秀奖（2007）
2.中国科学院王宽诚博士后工作奖（2007）
3.威廉希尔体育app下载“青年突击手”（2013）
4.威廉希尔体育app下载“优秀班主任”（2016）
5.威廉希尔体育app下载“十佳班主任”（2020）
6.指导本科生获湖北省第十一届挑战杯老员工课外学术科技作品竞赛二等奖（2017）
7.指导本科生获湖北省第十二届挑战杯老员工课外学术科技作品竞赛二等奖（2019）
8.指导本科生获湖北省第十三届挑战杯老员工课外学术科技作品竞赛二等奖（2021）
9.指导本科生获湖北省第八届老员工化学（化工）学术创新成果报告会二等奖（2015）
10.指导本科生获湖北省第十届老员工化学（化工）学术创新成果报告会二等奖（2017）
11.指导本科生获湖北省第十一届老员工化学（化工）学术创新成果报告会二等奖（2018）
12.指导本科生获湖北省第十一届老员工化学（化工）学术创新成果报告会一等奖（2018）
13.指导本科生获湖北省第十二届老员工化学（化工）学术创新成果报告会一等奖（2019）
14.指导本科生获湖北省第十三届老员工化学（化工）学术创新成果报告会一等奖（2020）
15.指导本科生获湖北省第十三届老员工化学（化工）学术创新成果报告会一等奖（2020）
16.指导本科生获湖北省第十四届老员工化学（化工）学术创新成果报告会一等奖（2021）
17.指导本科生获湖北省第十五届老员工化学（化工）学术创新成果报告会一等奖（2022）
18.指导本科生获湖北省第十五届老员工化学（化工）学术创新成果报告会一等奖（2022）
19.指导本科生获第十二届全国老员工化学实验邀请赛二等奖（有机方向，2021）
20.指导本科生获第八届湖北省老员工化学实验技能竞赛专业组一等奖（有机方向，2021）
代表性论著：
1.Qian-Na Peng, Hui-Juan Wang, Xing-Yu Wang,Fa-Bao Li,* Li Liu, Xiao-Li Wang, Ping Wu,* and Chao-Yang Liu*“Synthesis ofPendantFullerene DimersbyAminomethylationReaction ofFulleropyrrolidinesBearing KetoneMoieties”Org. Biomol. Chem.2023,21,DOI: 10.1039/d3ob00365e.
2.Xiu-Shan Liu, Hui-Juan Wang, Fei-Lun Wu, Jing-Wen Huo, Xing-Yu Wang,Fa-Bao Li,* Rui Sun, Li Liu, and Chao-Yang Liu*“Cu(OAc)2-Mediated Synthesis of Fullerodihydropyridine-3-ones via the Reaction of [60]Fullerene with β-Substituted Ethylamines in the Absence or Presence of Arylacetaldehydes”Chin. J. Chem.2023,41, 1557-1565.(Inside Back Cover)
3.Fa-Bao Li,* “ChemicalReactivity andAdditionPattern on C60and C70”,in Handbook of Fullerene Science and Technology, Xing Lu, Takeshi Akasaka and Zdeněk Slanina, Ed., Springer,Chapter 32,2022, 1-40.DOI: 10.1007/978-981-13-3242-5_32-1.Online ISBN: 978-981-13-3242-5.(Invited Book Chapter)
4.Rui Sun, Ming-Ding Chai, Xiong Liu, Ying Wang,Fa-Bao Li,* Xiu-Shan Liu, Xu-Feng Liu,* Li Liu, and Abdullah M. Asiric“Manganese(III)Acetate-MediatedSynthesis ofN-SubstitutedFulleropyrrolinesvia theReaction of [60]Fullerene withα-MonosubstitutedAcetaldehydes andPrimaryAmines”Org. Biomol. Chem.2021,19, 10139-10155.
5.Xiong Liu, Xing-Yu Wang, Rui Sun, Min-Rong Huang, Xiu-Shan Liu, Hui-Juan Wang,Fa-Bao Li,* Xu-Feng Liu,* Li Liu, and Chao-Yang Liu*“Fullerotetrahydroquinolines: TfOH/TsOH.H2O-Mediated One-Pot Two-Step Synthesis andN-Alkylation/Acylation/Carboamidation Reaction”Adv. Synth. Catal.2021,363,4399-4421.
6.Hui Wang,Mengting Chen,Fa-Bao Li,* Rui Sun, Pang Wang,Fanghao Ye,Huijun Zhang, Weiqiang Miao, Dan Liu,* and Tao Wang*“ThiopheneTerminated Fullerene Derivatives for InterfacialModificationtoward High Efficiency MAPbI3Perovskite Solar Cells”ACS Appl. Energy Mater.2020,3,9824-9832.
7.Hui Wang,Fa-Bao Li, Pang Wang, Rui Sun, Wan Ma, Mengting Chen, Weiqiang Miao, Dan Liu,* and Tao Wang*“ChlorinatedFullereneDimersforInterfacialEngineering towardStablePerovskiteSolarCells with 22.3 %Efficiency”Adv.EnergyMater.2020,10,2000615.
8.Yun-Fei Li, Kun Wang, Hui-Juan Wang,Fa-Bao Li,* Rui Sun, Jia-Xing Li,* Li Liu, Chao-Yang Liu,* and Abdullah M. Asiri,“FacileAccess toAmino-SubstitutedCyclopentafullerenes:NovelReactionof [60]Fullerenewithβ-SubstitutedPropionaldehydesandSecondaryAminesin theAbsence/Presence ofMagnesiumPerchlorate”Org. Biomol. Chem.2020,18,6866-6880.
9.Wan Ma, Kun Wang, Cheng Huang, Hui-Juan Wang,Fa-Bao Li,* Rui Sun, Li Liu, Chao-Yang Liu,* and Abdullah M. Asiri“Stereoselective Synthesis ofAmino-Substituted CyclopentafullerenesPromoted by MagnesiumPerchlorate/Ferric Perchlorate”Org. Biomol. Chem.2020,18,964-974.
10.Yun-Fei Li, Duo Zhang, Hui-Juan Wang,Fa-Bao Li,*Liang Sun,Li Liu,Chao-Yang Liu,* Abdullah M. Asiri,and Khalid A. Alamry“Metal-FreeSynthesis ofN-Alkyl-2,5-Unsubstituted/MonosubstitutedFulleropyrrolidines: Reactionof [60]Fullerene withPolyformaldehydeand Amines”J. Org. Chem.2019,84,2922-2932.
11.Gang Huang,Meng Zhang,Hui-Juan Wang,Fa-Bao Li,*Fei Yang,Li Liu, Chao-Yang Liu,*Abdullah M. Asiri, and Khalid A. Alamry “Metal-FreeSynthesis of Fulleropyrrolidin-2-ols: NovelReactionof [60]Fullerene withAmines and2,2-Disubstituted Acetaldehydes”Org. Biomol. Chem.2018,16, 7648-7656.
12.Meng Zhang, Hui-Juan Wang,Fa-Bao Li,*Xin-Xin Zhong, Yongshun Huang, Li Liu,*Chao-Yang Liu,*Abdullah M. Asiri, and Khalid A. Alamry“StereoselectiveSynthesisofN-Ethyl-2-Arylvinyl-5-MethylFulleropyrrolidines: Reaction of[60]Fullerene withAromatic Aldehydesand Triethylamine/Diethylaminein the Absence or Presence ofManganese(III)Acetate”Org. Biomol. Chem.2018,16,2975-2985.
13.Cheng Huang, Gang Huang, Hui-Juan Wang,Fa-Bao Li,*Zhen Wang, Yongshun Huang, Li Liu, and Chao-Yang Liu*“N-Alkylation of Fulleropyrrolidines by Aminomethylation Reaction of Ketones/Arylboronic Acids”Adv. Synth. Catal.2018,360,3732-3750.
14.Jie Peng,Gang Huang,Hui-Juan Wang,Fa-Bao Li,*Cheng Huang,Jun-Jun Xiang, Yongshun Huang, Li Liu,*Chao-Yang Liu,*Abdullah M. Asiri, and Khalid A. Alamry“TEMPO-Mediated SynthesisofTetrahydropyridinofullerenes: Reaction of[60]Fullerene withα-Methyl-SubstitutedArylmethanaminesand Aldehydesin the Presence of4-Dimethylaminopyridine”J. Org. Chem.2018,83,85-95.
15.Hui Wang,Feilong Cai, Meng Zhang, Pang Wang, Jiaxu Yao, Robert S. Gurney,Fa-Bao Li, Dan Liu,andTao Wang*“Halogen-substituted Fullerene Derivatives for Interface Engineering ofPerovskite Solar Cells”J. Mater. Chem. A,2018,6, 21368-21378.
16.Jie Peng, Jun-Jun Xiang, Hui-Juan Wang,Fa-Bao Li,*Yong-Shun Huang, Li Liu,*Chao-Yang Liu,*Abdullah M. Asiri, and Khalid A. Alamry“DMAP-Mediated SynthesisofFulleropyrrolines: Reaction of[60]Fullerene withAromatic Aldehydes andArylmethanaminesin the Absence or Presence ofManganese(III)Acetate”J. Org. Chem.2017,82,9751-9764.
17.Meng Zhang,Hui-Juan Wang,Fa-Bao Li,*Xin-Xin Zhong,Yong-Shun Huang,Li Liu,*Chao-Yang Liu,*Abdullah M. Asiri,andKhalid A. Alamry“Synthesis of 2-Aryl-5-alkyl-fulleropyrrolidines:Metal-Free-MediatedReaction of [60]Fullerene withAromaticAldehydesandInactivePrimary Amines”J. Org. Chem.2017,82,8617-8627.
18.Fa-Bao Liand Guan-Wu Wang* “Function Oriented Molecular Design: Fullerenes and Related Carbon Materials”, inEncyclopedia of Physical Organic Chemistry,Zerong Wang,Ed., John Wiley & Sons Inc., Hoboken,Volume 3, Chapter 9,2017, 1-75. Online ISBN: 9781118470459.(Invited Book Chapter)
19.Jun Wu, Chun-Xiang Liu, Hui-Juan Wang,Fa-Bao Li,* Ji-Long Shi, Li Liu, Jia-Xing Li,* Chao-Yang Liu,* and Yong-Shun Huang“Cu(OAc)2-MediatedReaction of [60]Fullerene withAldehydesand Primary Aminesfor the Synthesis of Fulleropyrrolines”J. Org. Chem.2016,81, 9296-9307.
20.Ji-Long Shi,Xiao-Feng Zhang,Hui-Juan Wang,Fa-Bao Li,* Xin-Xin Zhong, Chun-Xiang Liu, Li Liu,*Chao-Yang Liu,* Hai-Mei Qin,*and Yong-Shun Huang“A Protocol for the Preparation of 2,5-Diaryl Fulleropyrrolidines: Thermal Reaction of [60]Fullerene with Aromatic Aldehydes and Arylmethanamines”J. Org. Chem.2016,81,7662-7674.
21.Ji-Long Shi,Fa-Bao Li,*Xiao-Feng Zhang,Jun Wu, Hong-Yu Zhang, Jie Peng, Chun-Xiang Liu, Li Liu,*Ping Wu, and Jia-Xing Li“Synthesis and Functionalization of Symmetrical 2,5-Diaryl Fulleropyrrolidines: Ferric Perchlorate-Mediated One-Step Reaction of [60]Fullerene with Arylmethanamines”J. Org. Chem.2016,81, 1769-1777.
22.Xiao-Feng Zhang,Fa-Bao Li,*Jun Wu, Ji-Long Shi, Zhan Liu, and Li Liu* “Synthesis of Fullerene-FusedDioxanes/Dioxepanes: Ferric PerchlorateMediated One-Step Reaction of [60]Fullerene with Diols”J. Org. Chem.2015,80, 6037-6043.
23.Tong-Xin Liu,Fa-Bao Li,Dian-Bing Zhou,and Guan-Wu Wang* “Ferric Perchlorate-Promoted Reaction of [60]Fullerene with N-Sulfonyl Aldimines: Synthesis and Functionalization of Fulleroxazolidines”J. Org. Chem.2015,80, 11986-11992.
24.Xun You,Fa–Bao Li, and Guan–Wu Wang* “Synthesis of Ortho Acid Ester-Type 1,3-Dioxolanofullerenes: Radical Reaction of [60]Fullerene with Halocarboxylic Acids Promoted by Lead(IV) Acetate”J. Org. Chem.2014,79, 11155-11160.
25.Hai-Tao Yang,* Meng-Lei Xing, Ye-Fei Zhu, Xiao-Qiang Sun, Jiang Cheng, Chun-Bao Miao, andFa-Bao Li* “BF3·Et2O-Catalyzed Formal [3+2] Reaction of Aziridinofullerenes with Carbonyl Compounds”J. Org. Chem.2014,79, 1487–1492.
26.Fa-Bao Liand Guan-Wu Wang* “Fullerenes”, inKirk-Othmer Encyclopedia of Chemical Technology, Arza Seidel, Ed., John Wiley & Sons Inc.,Hoboken,2013, pp. 1-89. Online ISBN: 9780471238966.(Invited Book Chapter)
27.Fa–Bao Li, Xun You, Tong–Xin Liu, and Guan–Wu Wang* “Fullerenyl Boronic Esters: Ferric Perchlorate–Mediated Synthesis and Functionalization”Org. Lett.2012,14, 1800–1803.
28.Fa–Bao Li, Xun You, and Guan–Wu Wang* “Ferric Perchlorate–Mediated Synthesis of 1,2–Fullerenols C60(OCOR)(OH)”J. Org. Chem.2012,77, 6643–6647.
29.Tong–Xin Liu,Fa–Bao Li,and Guan–Wu Wang* “Synthesis of [60]Fullerene–Fused Tetrahydronaphthalene and Indane Derivatives via a Pathway Switched by Aluminum Chloride”Org. Lett.2011,13, 6130–6133.
30.Fa–Bao Li, Xun You, and Guan–Wu Wang* “Synthesis of Disubstituted [60]Fullerene–Fused Lactones: Ferric Perchlorate–Promoted Reaction of [60]Fullerene with Malonate Esters”Org. Lett.2010,12,4896–4899.
31.Fa–Bao Li, Tong–Xin Liu, Xun You, and Guan–Wu Wang* “A Facile Access to [60]Fullerene–Fused 1,3–Dioxolanes: Reaction of [60]Fullerene with Aldehydes/Ketones Promoted by Ferric Perchlorate”Org. Lett.2010,12, 3258–3261.
32.Fa–Bao Li, Tong–Xin Liu, Yong–Shun Huang, and Guan–Wu Wang* “Synthesis of Fullerene–Fused Lactones and Fullerenyl Esters: Radical Reaction of [60]Fullerene with Carboxylic Acids Promoted by Manganese(III) Acetate and Lead(IV) Acetate”J. Org. Chem.2009,74, 7743–7749.
33.Fa–Bao Li, Tong–Xin Liu, and Guan–Wu Wang* “Synthesis of Fullerooxazoles: Novel Reactions of [60]Fullerene with Nitriles Promoted by Ferric Perchlorate”J. Org. Chem.2008,73, 6417–6420.
34.Guan–Wu Wang,*Fa–Bao Li,and Yu Xu “Novel Functionalizations of [60]Fullerene–Fused Lactones”J. Org. Chem.2007,72, 4774–4778.
35.Guan–Wu Wang,*Fa–Bao Li,Zhong–Xiu Chen, Ping Wu, Bin Cheng, and Yu Xu “Synthesis of [60]Fullerene Acetals and Ketals: Reaction of [60]Fullerene with Aldehydes/Ketones and Alkoxides”J. Org. Chem.2007,72, 4779–4783.
36.Guan–Wu Wang,*Fa–Bao Li, and Ting–Hu Zhang “[60]Fullerene–Fused Lactones: Manganese(III) Acetate–Mediated Synthesis and Novel Reductive Ring Opening”Org. Lett.2006,8, 1355–1358.
37.Guan–Wu Wang* andFa–Bao Li“Cu(II) Acetate– and Mn(III) Acetate–Mediated Radical Reactionsof[60]Fullerenewith Ketonic Compounds”,Org. Biomol. Chem.2005,3, 794–797.
